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Solutions & Colligative Properties

Abnormal Molar Mass

A molar mass value obtained from colligative measurements that differs from the true value because the solute associates or dissociates.

M_normal = i × M_observed g/mol
States of Matter & Gas Laws

Absolute Zero

The lowest possible temperature, at which particles retain only their irreducible quantum zero-point motion.

0 K = −273.15 °C K
Foundations of Chemistry

Accuracy

The closeness of a measured value to the true or accepted value of the quantity being measured.

% error = |measured − true| / true × 100 Dimensionless
Acids, Bases & Salts

Acid

A substance that donates protons, produces hydrogen ions in water, or accepts a pair of electrons.

HA → H⁺ + A⁻ Dimensionless
Acids, Bases & Salts

Acid Dissociation Constant

The equilibrium constant for the ionisation of an acid in water, measuring its strength.

Ka = [H⁺][A⁻] / [HA] mol/L
Acids, Bases & Salts

Acid Strength and Molecular Structure

The structural factors that determine how readily a molecule releases a proton.

Dimensionless
Acids, Bases & Salts

Acidic Buffer

A buffer made from a weak acid and one of its salts, giving a pH below 7.

pH = pKa + log([salt]/[acid]) Dimensionless
Acids, Bases & Salts

Acidic Salt

A salt whose aqueous solution has a pH below 7, or one that still contains replaceable hydrogen.

Dimensionless
Acids, Bases & Salts

Acidic Solution

A solution in which the hydrogen ion concentration exceeds the hydroxide ion concentration.

[H⁺] > [OH⁻] mol/L
Acids, Bases & Salts

Acid–Base Indicator

A weak acid or base whose conjugate forms have distinctly different colours, used to signal the end point of a titration.

HIn ⇌ H⁺ + In⁻ Dimensionless
Acids, Bases & Salts

Acid–Base Titration

A titration in which an acid is neutralised by a base, or the reverse, monitored by an indicator or a pH meter.

M_aV_a / n_a = M_bV_b / n_b mol/L
Chemical Kinetics & Catalysis

Activated Complex

The transient arrangement of atoms present at the transition state, poised between reactants and products.

kJ/mol
Chemical Kinetics & Catalysis

Activation Energy

The minimum energy that colliding particles must possess for a reaction to occur.

Ea = E(transition state) − E(reactants) kJ/mol
Chemical Kinetics & Catalysis

Active Site

The specific region of a catalyst or enzyme at which the reacting molecules bind and are transformed.

Dimensionless
Chemical Equilibrium

Activity

The effective concentration of a species, corrected for non-ideal interactions with its surroundings.

a = γ c / c° Dimensionless
Chemical Equilibrium

Activity Coefficient

The factor by which a species' concentration must be multiplied to give its thermodynamic activity.

γ = a / c Dimensionless
Stoichiometry & Chemical Reactions

Activity Series

A ranking of metals in order of their tendency to lose electrons and form positive ions.

V
Stoichiometry & Chemical Reactions

Actual Yield

The mass of pure product actually isolated at the end of an experiment.

g
Biochemistry & Polymer Chemistry

Addition Polymerisation

Polymerisation in which unsaturated monomers add to one another with no loss of any atoms.

n CH₂=CH₂ → –(CH₂–CH₂)ₙ– Dimensionless
Stoichiometry & Chemical Reactions

Addition Reaction

A reaction in which two molecules combine to form a single larger product, with no atoms left over.

A + B → AB Dimensionless
Biochemistry & Polymer Chemistry

Adenosine Triphosphate

The nucleotide that acts as the universal energy currency of living cells.

ATP + H₂O → ADP + Pᵢ kJ/mol
Thermochemistry & Thermodynamics

Adiabatic Process

A process in which no heat is exchanged between the system and its surroundings.

q = 0, ΔU = w J
Chemical Kinetics & Catalysis

Adsorption

The accumulation of molecules of a gas or liquid on the surface of a solid.

mol/g
Solutions & Colligative Properties

Aerosol

A colloidal system in which solid or liquid particles are dispersed in a gas.

nm