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Chemical Equilibrium

ICE Table

A systematic tabulation of Initial, Change and Equilibrium amounts used to solve equilibrium problems.

mol/L
States of Matter & Gas Laws

Ideal Gas

A hypothetical gas whose particles have zero volume and exert no intermolecular forces, obeying pV = nRT exactly at all conditions.

pV = nRT Dimensionless
States of Matter & Gas Laws

Ideal Gas Law

The equation of state relating the pressure, volume, amount and absolute temperature of an ideal gas.

pV = nRT Various
Solutions & Colligative Properties

Ideal Solution

A solution in which the interactions between unlike molecules are identical to those between like molecules, so Raoult's law holds at all…

ΔH_mix = 0, ΔV_mix = 0 Dimensionless
Solutions & Colligative Properties

Immiscible Liquids

Two liquids that do not dissolve in one another and separate into distinct layers.

Dimensionless
Chemical Bonding & Molecular Structure

Incomplete Octet

A stable bonding arrangement in which the central atom carries fewer than eight valence electrons.

Dimensionless
Acids, Bases & Salts

Indicator Range

The span of pH over which an indicator's colour visibly changes, roughly one unit either side of its pKa.

pH = pK_In ± 1 Dimensionless
Biochemistry & Polymer Chemistry

Induced Fit Model

The model in which the active site changes shape on substrate binding to achieve a closer fit.

Dimensionless
Organic Chemistry

Inductive Effect

The permanent polarisation of a sigma bond caused by the differing electronegativity of the attached atoms.

−I and +I effects Dimensionless
Analytical Chemistry & Spectroscopy

Inductively Coupled Plasma Mass Spectrometry

A technique combining a plasma ion source with a mass spectrometer for ultra-trace multi-element analysis.

ppb
Analytical Chemistry & Spectroscopy

Infrared Spectroscopy

A technique that identifies functional groups from the infrared frequencies a molecule absorbs as its bonds vibrate.

ν̃ = (1/2πc)√(k/μ) cm⁻¹
Chemical Kinetics & Catalysis

Inhibitor

A substance that decreases the rate of a chemical reaction.

Dimensionless
Chemical Kinetics & Catalysis

Initial Rate Method

A technique for determining reaction orders by measuring the starting rate in a series of experiments with different initial concentrations.

rate₂/rate₁ = ([A]₂/[A]₁)^m mol/(L·s)
Atomic Structure & Periodicity

Inner Transition Element

An element of the lanthanide or actinide series, in which f orbitals are being filled.

(n−2)f orbitals filling Dimensionless
Chemical Kinetics & Catalysis

Instantaneous Rate

The rate of a reaction at one particular moment, given by the gradient of the concentration–time curve at that point.

rate = d[A]/dt mol/(L·s)
Chemical Kinetics & Catalysis

Integrated Rate Law

The equation obtained by integrating a differential rate law, giving concentration directly as a function of time.

varies with order mol/L
Analytical Chemistry & Spectroscopy

Integration in NMR

The measurement of the area under each NMR signal, which is proportional to the number of nuclei giving rise to it.

area ∝ number of nuclei Dimensionless
Foundations of Chemistry

Intensive Property

A property whose value is independent of the amount of substance present.

Various
Chemical Bonding & Molecular Structure

Intermolecular Forces

The comparatively weak attractions acting between separate molecules rather than within them.

kJ/mol
Thermochemistry & Thermodynamics

Internal Energy

The total kinetic and potential energy of all the particles within a system.

ΔU = q + w J
Inorganic & Coordination Chemistry

Interstitial Compound

A compound formed when small atoms occupy the spaces between metal atoms in a lattice.

Dimensionless
States of Matter & Gas Laws

Interstitial Void

An empty space between the packed spheres of a crystal lattice, capable of hosting a smaller ion or atom.

r_void / r_sphere = 0.225 or 0.414 Dimensionless
Analytical Chemistry & Spectroscopy

Iodometry

A redox titration in which iodine liberated by the analyte is titrated with standard thiosulfate.

I₂ + 2S₂O₃²⁻ → 2I⁻ + S₄O₆²⁻ mol/L
Foundations of Chemistry

Ion

An atom or group of atoms carrying a net electrical charge because its electron count differs from its proton count.

C (charge)