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Acids, Bases & Salts

Acid Dissociation Constant

The equilibrium constant for the ionisation of an acid in water, measuring its strength.

Formula / equation Ka = [H⁺][A⁻] / [HA]
Unit mol/L

In depth

A larger Ka means a stronger acid and a more extensively ionised solution. Because values span more than twenty orders of magnitude, they are usually quoted logarithmically as pKa. Ka is temperature-dependent but independent of concentration.

Examples in the real world

Ethanoic acid has Ka = 1.8 × 10⁻⁵; hydrofluoric acid 6.8 × 10⁻⁴; hydrocyanic acid only 6.2 × 10⁻¹⁰.