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Terms starting with S

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Atomic Structure & Periodicity

s-Block Elements

The elements of groups 1 and 2, plus helium, whose outermost electrons occupy an s orbital.

ns¹ or ns² Dimensionless
Electrochemistry & Redox

Sacrificial Anode

A block of reactive metal attached to a structure so that it corrodes preferentially and protects the structure.

Dimensionless
Acids, Bases & Salts

Salt

An ionic compound formed when the hydrogen of an acid is replaced by a metal or other cation.

acid + base → salt + water Dimensionless
Electrochemistry & Redox

Salt Bridge

A conducting connection between the two half-cells of a galvanic cell that completes the circuit and maintains electrical neutrality.

Dimensionless
Acids, Bases & Salts

Salt Hydrolysis

The reaction of a salt's ions with water to produce an acidic or alkaline solution.

A⁻ + H₂O ⇌ HA + OH⁻ mol/L
Analytical Chemistry & Spectroscopy

Sampling

The process of selecting a small portion of material that genuinely represents the bulk being analysed.

g
Inorganic & Coordination Chemistry

Sandwich Compound

An organometallic compound in which a metal atom is held between two parallel planar cyclic ligands.

e.g. Fe(C₅H₅)₂ Dimensionless
Stoichiometry & Chemical Reactions

Saponification

The alkaline hydrolysis of an ester, particularly a triglyceride, to give a carboxylate salt and an alcohol.

RCOOR′ + NaOH → RCOONa + R′OH Dimensionless
Biochemistry & Polymer Chemistry

Saturated Fat

A fat whose fatty acid chains contain only single carbon–carbon bonds.

Dimensionless
Solutions & Colligative Properties

Saturated Solution

A solution in dynamic equilibrium with undissolved solute, containing the maximum amount that will dissolve at that temperature.

rate dissolve = rate crystallise mol/L
Organic Chemistry

Saturation and Unsaturation

The distinction between compounds containing only single bonds and those containing multiple bonds or rings.

DoU = (2C + 2 + N − H − X)/2 Dimensionless
States of Matter & Gas Laws

Schottky Defect

A point defect in which equal numbers of cations and anions are missing from their lattice sites.

Dimensionless
Atomic Structure & Periodicity

Schrödinger Wave Equation

The fundamental equation of quantum mechanics whose solutions give the allowed energies and wavefunctions of a system.

Ĥψ = Eψ J
Nuclear & Radiochemistry

Scintillation Counter

A detector in which radiation causes a material to emit flashes of light that are counted and measured.

counts/s
Thermochemistry & Thermodynamics

Second Law of Thermodynamics

The total entropy of the universe increases in every spontaneous process.

ΔS_universe > 0 J/K
Chemical Kinetics & Catalysis

Second-Order Reaction

A reaction whose rate depends on the square of one concentration or on the product of two concentrations.

1/[A] = 1/[A]₀ + kt L/(mol·s)
Electrochemistry & Redox

Secondary Cell

A cell whose reaction can be reversed by an applied current, allowing it to be recharged and reused.

V
Analytical Chemistry & Spectroscopy

Secondary Standard

A solution whose concentration has been established by titration against a primary standard.

mol/L
Biochemistry & Polymer Chemistry

Secondary Structure

Local regular folding patterns of a polypeptide backbone stabilised by hydrogen bonds.

Dimensionless
Inorganic & Coordination Chemistry

Secondary Valence

In Werner's theory, the non-ionisable valence corresponding to the coordination number, satisfied by ligands in fixed spatial positions.

Dimensionless
Nuclear & Radiochemistry

Secular Equilibrium

The steady state reached when a long-lived parent supports a short-lived daughter at constant activity.

λ₁N₁ = λ₂N₂ Bq
Electrochemistry & Redox

Selective Discharge

The preferential reaction of one ion over others at an electrode during electrolysis.

V
Chemical Equilibrium

Selective Precipitation

The separation of ions from a mixture by adding a reagent that precipitates them one at a time.

mol/L
Chemical Kinetics & Catalysis

Selectivity

The ability of a catalyst to direct a reaction towards one particular product among several possible ones.

selectivity = desired product / total product Dimensionless