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Terms starting with P

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Atomic Structure & Periodicity

p-Block Elements

The elements of groups 13 to 18, in which the outermost electrons progressively fill p orbitals.

ns² np¹⁻⁶ Dimensionless
States of Matter & Gas Laws

Packing Efficiency

The percentage of the total volume of a unit cell that is actually occupied by the constituent particles.

(volume of atoms / cell volume) × 100 Dimensionless
Atomic Structure & Periodicity

Paramagnetism

Weak attraction into a magnetic field, shown by substances containing one or more unpaired electrons.

μ = √(n(n+2)) BM BM
Nuclear & Radiochemistry

Parent and Daughter Nuclide

The nuclide undergoing decay and the nuclide produced by that decay.

parent → daughter + radiation Dimensionless
States of Matter & Gas Laws

Partial Pressure

The pressure that one component of a gas mixture would exert if it alone occupied the whole volume.

p_i = x_i × p_total Pa
Chemical Equilibrium

Partition Coefficient

The equilibrium ratio of a solute's concentrations in two immiscible phases.

P = C₁ / C₂ Dimensionless
Solutions & Colligative Properties

Parts per Billion

A concentration unit expressing one part of solute per thousand million parts of solution.

ppb = (m_solute / m_solution) × 10⁹ ppb
Solutions & Colligative Properties

Parts per Million

A concentration unit expressing one part of solute per million parts of solution by mass or volume.

ppm = (m_solute / m_solution) × 10⁶ ppm
Thermochemistry & Thermodynamics

Path Function

A quantity whose value depends on the specific route taken between two states.

δq, δw J
Atomic Structure & Periodicity

Pauli Exclusion Principle

The rule that no two electrons in an atom may have the same set of all four quantum numbers.

n, l, mₗ, mₛ must differ Dimensionless
Nuclear & Radiochemistry

Penetrating Power

The depth to which a given type of radiation can travel into a material before being absorbed.

mm
Biochemistry & Polymer Chemistry

Peptide Bond

The amide linkage joining the carboxyl group of one amino acid to the amino group of the next.

–CO–NH– Dimensionless
Foundations of Chemistry

Percentage Composition

The proportion by mass of each element in a compound, expressed as a percentage of the total mass.

% element = (n × A_r / M_r) × 100 Dimensionless
Stoichiometry & Chemical Reactions

Percentage Purity

The proportion of a sample that consists of the desired compound, expressed as a percentage of the total mass.

% purity = (mass pure / mass sample) × 100 Dimensionless
Stoichiometry & Chemical Reactions

Percentage Yield

The actual yield expressed as a percentage of the theoretical yield.

% yield = (actual / theoretical) × 100 Dimensionless
Atomic Structure & Periodicity

Period

A horizontal row of the periodic table, corresponding to one principal quantum number of the valence shell.

Dimensionless
Atomic Structure & Periodicity

Periodic Law

The principle that the properties of the elements are periodic functions of their atomic numbers.

Dimensionless
Atomic Structure & Periodicity

Periodic Table

The tabular arrangement of the chemical elements by increasing atomic number, grouping those with similar properties in vertical columns.

Dimensionless
Chemical Equilibrium

Perturbation and Re-equilibration

The disturbance of an equilibrium followed by its relaxation to a new equilibrium state.

s
Acids, Bases & Salts

pH

The negative logarithm to base ten of the hydrogen ion concentration, measuring the acidity of a solution.

pH = −log[H⁺] Dimensionless
Acids, Bases & Salts

pH Scale

The conventional scale, usually running from 0 to 14, on which the acidity or alkalinity of aqueous solutions is expressed.

0 (acidic) – 7 (neutral) – 14 (alkaline) Dimensionless
States of Matter & Gas Laws

Phase Diagram

A pressure–temperature plot showing which phase of a substance is thermodynamically stable under any given conditions.

Pa, K
Chemical Equilibrium

Phase Equilibrium

The condition in which two or more phases of a substance coexist with no net transfer between them.

μ_phase1 = μ_phase2 Dimensionless
Organic Chemistry

Phenol

A compound in which a hydroxyl group is bonded directly to an aromatic ring.

C₆H₅–OH Dimensionless