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Thermochemistry & Thermodynamics

Second Law of Thermodynamics

The total entropy of the universe increases in every spontaneous process.

Formula / equation ΔS_universe > 0
Unit J/K

In depth

The second law establishes the direction of time in physical processes and explains why energy spontaneously disperses. A system's own entropy may fall, but only if the surroundings gain more, which is how living organisms and refrigerators maintain internal order at the cost of greater disorder outside.

Examples in the real world

Heat never flows spontaneously from a cold body to a hot one; a shattered glass never reassembles.