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Chemical Equilibrium

Selective Precipitation

The separation of ions from a mixture by adding a reagent that precipitates them one at a time.

Unit mol/L

In depth

Because the ions have different solubility products, the least soluble compound precipitates first and can be filtered off before the next begins to appear. Careful control of reagent concentration — often by controlling pH — makes very clean separations possible.

Examples in the real world

Passing H₂S into acidified solution precipitates CuS but leaves ZnS dissolved until the solution is made alkaline.