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Acids, Bases & Salts

Salt Hydrolysis

The reaction of a salt's ions with water to produce an acidic or alkaline solution.

Formula / equation A⁻ + H₂O ⇌ HA + OH⁻
Unit mol/L

In depth

Only ions derived from a weak parent acid or base hydrolyse appreciably; those from strong parents are spectators. The anion of a weak acid generates hydroxide, while the cation of a weak base generates hydrogen ions, and the resulting pH reflects which effect dominates.

Examples in the real world

Sodium carbonate solution is alkaline; ammonium chloride solution is acidic; sodium chloride is neutral.