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Terms starting with I

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Chemical Bonding & Molecular Structure

Ionic Bond

The electrostatic attraction between oppositely charged ions formed by the complete transfer of electrons from one atom to another.

F ∝ q₁q₂ / r² kJ/mol
Chemical Equilibrium

Ionic Equilibrium

An equilibrium involving ions in solution, such as the dissociation of weak electrolytes or the dissolution of sparingly soluble salts.

mol/L
Chemical Equilibrium

Ionic Product

The product of the ion concentrations actually present in a solution, each raised to its stoichiometric power.

Q_sp = [A⁺]^m[B⁻]^n Various
Acids, Bases & Salts

Ionic Product of Water

The equilibrium constant for the self-ionisation of water, equal to the product of the hydrogen and hydroxide ion concentrations.

Kw = [H⁺][OH⁻] = 1.0 × 10⁻¹⁴ mol²/L²
Atomic Structure & Periodicity

Ionic Radius

The effective radius of an ion within a crystal lattice, deduced from measured interionic distances.

pm
Chemical Equilibrium

Ionic Strength

A measure of the total concentration of ionic charge in a solution.

I = ½ Σ c_i z_i² mol/L
Atomic Structure & Periodicity

Ionisation Energy

The minimum energy needed to remove the most loosely held electron from one mole of gaseous atoms in their ground state.

X(g) → X⁺(g) + e⁻ kJ/mol
Inorganic & Coordination Chemistry

Ionisation Isomerism

Isomerism arising when an anion inside the coordination sphere exchanges places with the counter ion outside it.

Dimensionless
Nuclear & Radiochemistry

Ionising Radiation

Radiation with enough energy to remove electrons from atoms, creating ions.

eV
Chemical Bonding & Molecular Structure

Ion–Dipole Interaction

The attraction between an ion and the oppositely charged end of a polar molecule.

E ∝ q μ / r² kJ/mol
Thermochemistry & Thermodynamics

Irreversible Process

A real process that passes through non-equilibrium states and cannot be reversed without leaving a permanent change in the surroundings.

ΔS_universe > 0 J/K
Stoichiometry & Chemical Reactions

Irreversible Reaction

A reaction that proceeds essentially to completion, with negligible conversion back to reactants.

A + B → C Dimensionless
Atomic Structure & Periodicity

Isobar

One of a set of atoms of different elements that share the same mass number but have different atomic numbers.

same A, different Z Dimensionless
Thermochemistry & Thermodynamics

Isobaric Process

A process carried out at constant pressure.

q_p = ΔH J
Thermochemistry & Thermodynamics

Isochoric Process

A process carried out at constant volume, so that no expansion work is done.

w = 0, q_V = ΔU J
Biochemistry & Polymer Chemistry

Isoelectric Point

The pH at which a molecule carries no net electrical charge.

pI = (pKa₁ + pKa₂)/2 Dimensionless
Atomic Structure & Periodicity

Isoelectronic Species

Atoms or ions that possess the same number of electrons and the same electron configuration.

Dimensionless
Thermochemistry & Thermodynamics

Isolated System

A system that exchanges neither energy nor matter with its surroundings.

ΔU = 0 Dimensionless
Organic Chemistry

Isomerism

The existence of two or more compounds with the same molecular formula but different arrangements of atoms.

Dimensionless
Inorganic & Coordination Chemistry

Isomerism in Coordination Compounds

The existence of complexes with the same formula but different structures or spatial arrangements.

Dimensionless
States of Matter & Gas Laws

Isomorphism

The property of two or more different substances crystallising in the same structural form.

Dimensionless
Thermochemistry & Thermodynamics

Isothermal Process

A process carried out at constant temperature, with heat exchanged as needed to maintain it.

ΔU = 0 (ideal gas), w = −nRT ln(V₂/V₁) J
Atomic Structure & Periodicity

Isotone

One of a set of nuclides that contain the same number of neutrons but different numbers of protons.

same N, different Z Dimensionless
Solutions & Colligative Properties

Isotonic Solution

A solution having the same osmotic pressure as another, so that no net osmotic flow occurs between them.

π₁ = π₂ atm