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Thermochemistry & Thermodynamics

Isolated System

A system that exchanges neither energy nor matter with its surroundings.

Formula / equation ΔU = 0
Unit Dimensionless

In depth

An isolated system's internal energy is constant, so any process within it must simply redistribute energy internally. True isolation is unattainable, but a well-insulated vacuum flask approximates it closely enough for practical calorimetry. The entropy of an isolated system can never decrease.

Examples in the real world

A sealed vacuum flask over a short period; the universe as a whole, taken as the ultimate isolated system.