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Thermochemistry & Thermodynamics

Isochoric Process

A process carried out at constant volume, so that no expansion work is done.

Formula / equation w = 0, q_V = ΔU
Unit J

In depth

An isochoric process takes place in a rigid sealed container. Because the volume cannot change, no pressure–volume work is possible and all heat exchanged appears as a change in internal energy, which is why bomb calorimetry measures ΔU rather than ΔH.

Examples in the real world

Combustion inside a sealed steel bomb; heating a gas in a rigid cylinder so its pressure rises.