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Chemical Bonding & Molecular Structure

Ionic Bond

The electrostatic attraction between oppositely charged ions formed by the complete transfer of electrons from one atom to another.

Formula / equation F ∝ q₁q₂ / r²
Unit kJ/mol

In depth

Ionic bonding is favoured when electronegativity differs by more than about 1.7, typically between a metal and a non-metal. The attraction is non-directional, so ions pack into extended three-dimensional lattices rather than discrete molecules, giving high melting points, brittleness and conductivity when molten or dissolved.

Examples in the real world

Sodium chloride, magnesium oxide (melting at 2852 °C because of its 2+/2− charges) and calcium fluoride.