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Nuclear & Radiochemistry

Radiometric Dating

The general technique of determining the age of a sample from the decay of a radioactive nuclide it contains.

t = (1/λ) ln(1 + D/P) years
Nuclear & Radiochemistry

Radiopharmaceutical

A radioactive compound administered to a patient for diagnosis or treatment.

MBq
Nuclear & Radiochemistry

Radiotherapy

The medical use of ionising radiation to destroy cancerous tissue.

Gy
Analytical Chemistry & Spectroscopy

Raman Spectroscopy

A vibrational technique based on the small shift in frequency of light scattered inelastically by molecules.

Δν̃ = ν̃_incident − ν̃_scattered cm⁻¹
Analytical Chemistry & Spectroscopy

Random Error

An error that varies unpredictably in size and direction between repeated measurements.

Various
Solutions & Colligative Properties

Raoult's Law

The partial vapour pressure of each component of an ideal solution equals its mole fraction times its pure vapour pressure.

p_A = x_A p°_A Pa
Chemical Kinetics & Catalysis

Rate Constant

The proportionality constant in a rate law, characteristic of a given reaction at a given temperature.

k = A e^(−Ea/RT) Various
Chemical Kinetics & Catalysis

Rate Law

An experimentally determined equation expressing reaction rate as a function of reactant concentrations.

rate = k[A]^m[B]^n mol/(L·s)
Chemical Kinetics & Catalysis

Rate-Determining Step

The slowest step in a reaction mechanism, which limits the overall rate.

Dimensionless
Stoichiometry & Chemical Reactions

Reactant

A starting substance that is consumed during a chemical reaction.

mol
Chemical Kinetics & Catalysis

Reaction Intermediate

A species produced in one step of a mechanism and consumed in a later one, so it does not appear in the overall equation.

mol/L
Chemical Kinetics & Catalysis

Reaction Mechanism

The detailed sequence of elementary steps by which reactants are converted into products.

Dimensionless
Chemical Equilibrium

Reaction Quotient

The same ratio as the equilibrium constant but evaluated with the concentrations actually present at any moment.

Q = [C]^c[D]^d / [A]^a[B]^b Various
Chemical Kinetics & Catalysis

Reaction Rate

The change in concentration of a reactant or product per unit time.

rate = −Δ[A]/(aΔt) = Δ[P]/(pΔt) mol/(L·s)
Foundations of Chemistry

Reagent

A substance added to a system to bring about a chemical reaction or to test for the presence of another substance.

Dimensionless
States of Matter & Gas Laws

Real Gas

An actual gas whose behaviour deviates from the ideal gas law because its molecules occupy volume and attract one another.

Z = pV / nRT ≠ 1 Dimensionless
Stoichiometry & Chemical Reactions

Rearrangement Reaction

A reaction in which the atoms of a molecule are reorganised to give a structural isomer.

A → A′ (isomer) Dimensionless
Electrochemistry & Redox

Redox Couple

The oxidised and reduced forms of the same species, considered together as a conjugate pair.

Ox / Red V
Stoichiometry & Chemical Reactions

Redox Reaction

A reaction in which electrons are transferred, so that one species is oxidised while another is reduced.

Ox₁ + Red₂ → Red₁ + Ox₂ V
Analytical Chemistry & Spectroscopy

Redox Titration

A titration in which the reaction between titrant and analyte involves electron transfer.

mol/L
Electrochemistry & Redox

Reducing Agent

A species that donates electrons to another substance and is itself oxidised in the process.

V
Biochemistry & Polymer Chemistry

Reducing Sugar

A sugar with a free aldehyde or ketone group that can reduce mild oxidising agents.

Dimensionless
Electrochemistry & Redox

Reduction

The gain of electrons by a species, accompanied by a decrease in its oxidation number.

Xⁿ⁺ + n e⁻ → X Dimensionless
Electrochemistry & Redox

Reference Electrode

A half-cell with a stable, known and reproducible potential, used as a fixed point against which other potentials are measured.

V