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Chemical Kinetics & Catalysis

Reaction Mechanism

The detailed sequence of elementary steps by which reactants are converted into products.

Unit Dimensionless

In depth

A valid mechanism must add up to the overall equation and predict the observed rate law. Because several mechanisms may fit the same data, additional evidence — isotopic labelling, stereochemistry, intermediate detection — is used to discriminate between them. A mechanism can be disproved but never finally proved.

Examples in the real world

The SN1 mechanism's two steps explaining why the reaction is first order and gives a racemic product.