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Electrochemistry & Redox

Anodising

An electrolytic process that thickens the natural protective oxide layer on a metal, especially aluminium.

2Al + 3H₂O → Al₂O₃ + 6H⁺ + 6e⁻ μm
Organic Chemistry

Anti-Markovnikov Addition

Addition in which the hydrogen attaches to the carbon bearing fewer hydrogens, reversing the normal regiochemistry.

Dimensionless
Chemical Bonding & Molecular Structure

Antibonding Molecular Orbital

A molecular orbital higher in energy than its parent atomic orbitals, whose occupation destabilises the molecule.

ψ* = ψ_A − ψ_B Dimensionless
Chemical Equilibrium

Approach to Equilibrium

The time-dependent process by which a reacting system moves towards its equilibrium composition.

s
Solutions & Colligative Properties

Aqueous Solution

A solution in which water is the solvent, denoted by the state symbol (aq).

mol/L
Organic Chemistry

Arene

An aromatic hydrocarbon containing one or more benzene rings.

CₙH₂ₙ₋₆ Dimensionless
Organic Chemistry

Aromaticity

The special stability of planar cyclic molecules with a continuous, fully conjugated system of delocalised pi electrons.

planar, cyclic, conjugated, 4n+2 π kJ/mol
Chemical Kinetics & Catalysis

Arrhenius Equation

The equation describing how a rate constant varies with temperature and activation energy.

k = A e^(−Ea/RT) Various
Acids, Bases & Salts

Arrhenius Theory

The theory defining an acid as a substance that produces H⁺ ions in water and a base as one that produces OH⁻ ions.

HA → H⁺ + A⁻; BOH → B⁺ + OH⁻ Dimensionless
Nuclear & Radiochemistry

Artificial Radioactivity

Radioactivity in nuclides created by bombarding stable nuclei with particles rather than found in nature.

Bq
Solutions & Colligative Properties

Association

The joining of solute molecules in solution into larger aggregates, reducing the effective number of particles.

nA → Aₙ Dimensionless
Chemical Equilibrium

Association Constant

The equilibrium constant for the combination of two species into a single associated entity, the reciprocal of the dissociation constant.

Ka = 1 / Kd L/mol
Foundations of Chemistry

Atom

The smallest particle of an element that retains the chemical identity of that element.

Dimensionless
Analytical Chemistry & Spectroscopy

Atomic Absorption Spectroscopy

A technique that measures the concentration of a metal from the light its free gaseous atoms absorb.

A = εlc ppm
Analytical Chemistry & Spectroscopy

Atomic Emission Spectroscopy

A technique that identifies and quantifies elements from the light their excited atoms emit.

ppm
Atomic Structure & Periodicity

Atomic Emission Spectrum

The pattern of discrete wavelengths emitted when excited atoms of an element return to lower energy states.

ΔE = hν nm
Foundations of Chemistry

Atomic Mass Unit

A mass unit defined as exactly one twelfth the mass of a free, unbound carbon-12 atom in its ground state.

1 u = 1.66053907 × 10⁻²⁷ kg u (Da)
Atomic Structure & Periodicity

Atomic Number

The number of protons in the nucleus of an atom, which uniquely identifies the element.

Z = number of protons Dimensionless
Atomic Structure & Periodicity

Atomic Orbital

A mathematical function describing the region around a nucleus where an electron of given energy is most likely to be found.

|ψ|² = probability density Dimensionless
Atomic Structure & Periodicity

Atomic Radius

A measure of the size of an atom, usually taken as half the distance between the nuclei of two bonded identical atoms.

r = d(X–X) / 2 pm
Foundations of Chemistry

Atomicity

The number of atoms present in one molecule of an element.

Dimensionless
Atomic Structure & Periodicity

Aufbau Principle

The rule that electrons occupy the lowest-energy orbital available before filling higher-energy ones.

fill in order of increasing (n + l) Dimensionless
Chemical Kinetics & Catalysis

Autocatalysis

Catalysis of a reaction by one of its own products.

Dimensionless
States of Matter & Gas Laws

Average Kinetic Energy

The mean translational kinetic energy of the particles in a sample, dependent only on absolute temperature.

KE = (3/2)kT per molecule J