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Chemical Bonding & Molecular Structure

Incomplete Octet

A stable bonding arrangement in which the central atom carries fewer than eight valence electrons.

Unit Dimensionless

In depth

Common for beryllium, boron and aluminium, an incomplete octet leaves a vacant p orbital that makes these species strong Lewis acids, eager to accept a lone pair. Many relieve the deficiency by dimerising through bridging bonds.

Examples in the real world

BF₃ has six electrons on boron and readily forms F₃B←NH₃; AlCl₃ dimerises to Al₂Cl₆ with chloride bridges.