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Terms starting with F

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Atomic Structure & Periodicity

f-Block Elements

The lanthanides and actinides, in which electrons fill the f orbitals of the antepenultimate shell.

(n−2)f¹⁻¹⁴ Dimensionless
States of Matter & Gas Laws

Face-Centred Cubic

A cubic arrangement with particles at the eight corners and at the centre of each of the six faces.

4 atoms per cell, 74% packing Dimensionless
Chemical Bonding & Molecular Structure

Fajans' Rules

A set of guidelines predicting how much covalent character an ionic bond will have.

Dimensionless
Electrochemistry & Redox

Faraday Constant

The electric charge carried by one mole of electrons.

F = 96,485 C/mol C/mol
Electrochemistry & Redox

Faraday's First Law of Electrolysis

The mass of a substance liberated at an electrode is directly proportional to the quantity of electricity passed.

m = Z I t g
Electrochemistry & Redox

Faraday's Second Law of Electrolysis

When the same quantity of electricity passes through different electrolytes, the masses deposited are proportional to their chemical…

m₁/m₂ = E₁/E₂ g
Biochemistry & Polymer Chemistry

Fatty Acid

A long-chain carboxylic acid, usually with an even number of carbon atoms.

CH₃(CH₂)ₙCOOH g/mol
Stoichiometry & Chemical Reactions

Fermentation

The anaerobic enzymatic conversion of sugars into simpler products such as ethanol and carbon dioxide.

C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂ Dimensionless
Foundations of Chemistry

Filtration

A separation technique that removes suspended solid particles from a fluid by passing the mixture through a porous medium.

Dimensionless
Analytical Chemistry & Spectroscopy

Fingerprint Region

The complex lower-frequency part of an infrared spectrum, below about 1500 cm⁻¹, unique to each compound.

400–1500 cm⁻¹ cm⁻¹
Thermochemistry & Thermodynamics

First Law of Thermodynamics

The energy of an isolated system is constant; energy can be converted between forms but never created or destroyed.

ΔU = q + w J
Chemical Kinetics & Catalysis

First-Order Reaction

A reaction whose rate is directly proportional to the concentration of a single reactant.

ln[A] = ln[A]₀ − kt s⁻¹
Analytical Chemistry & Spectroscopy

Flame Test

A qualitative test in which a sample is heated in a flame and identified by the characteristic colour emitted.

nm
Inorganic & Coordination Chemistry

Flux

A substance added during smelting to combine with the gangue and form a fusible slag.

Dimensionless
Solutions & Colligative Properties

Foam

A colloidal system in which gas bubbles are dispersed throughout a liquid or solid medium.

nm
Chemical Bonding & Molecular Structure

Formal Charge

The hypothetical charge on an atom in a Lewis structure assuming all bonding electrons are shared equally.

FC = V − L − B/2 Dimensionless
Foundations of Chemistry

Formula Unit

The simplest whole-number ratio of ions represented in the empirical formula of an ionic or network compound.

Dimensionless
Foundations of Chemistry

Fractional Distillation

A distillation carried out through a packed or plated column that repeatedly vaporises and condenses the mixture to separate liquids with…

Dimensionless
Analytical Chemistry & Spectroscopy

Fragmentation Pattern

The characteristic set of smaller ions produced when a molecular ion breaks apart in a mass spectrometer.

Da
Electrochemistry & Redox

Free Energy and Cell Potential

The relation linking the Gibbs energy change of a cell reaction to the electromotive force it generates.

ΔG = −nFE kJ/mol
Thermochemistry & Thermodynamics

Free Energy and Equilibrium Constant

The relation connecting the standard Gibbs energy change of a reaction to its equilibrium constant.

ΔG° = −RT ln K kJ/mol
Organic Chemistry

Free Radical

A highly reactive species containing an unpaired electron.

Dimensionless
Chemical Kinetics & Catalysis

Free Radical Chain Mechanism

A chain mechanism in which the propagating intermediates are species bearing unpaired electrons.

X· + RH → HX + R· Dimensionless
States of Matter & Gas Laws

Freezing Point

The temperature at which a liquid becomes a solid, numerically identical to the melting point of the pure substance.

ΔT_f = K_f × m °C