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Foundations of Chemistry

Formula Unit

The simplest whole-number ratio of ions represented in the empirical formula of an ionic or network compound.

Unit Dimensionless

In depth

Ionic solids are continuous three-dimensional lattices with no discrete molecules, so the formula unit is a bookkeeping device rather than a real particle. Its mass, the formula mass, plays exactly the role that molecular mass plays for covalent substances in mole calculations.

Examples in the real world

NaCl is one Na⁺ and one Cl⁻ (formula mass 58.44); CaF₂ is one Ca²⁺ and two F⁻ ions.