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Thermochemistry & Thermodynamics

First Law of Thermodynamics

The energy of an isolated system is constant; energy can be converted between forms but never created or destroyed.

Formula / equation ΔU = q + w
Unit J

In depth

The first law is the principle of energy conservation applied to thermodynamic systems. It rules out perpetual motion of the first kind but says nothing about direction — it permits heat to flow from cold to hot, which the second law then forbids.

Examples in the real world

A gas absorbing 500 J of heat while doing 200 J of work gains exactly 300 J of internal energy.