Home Wikituition Browse all terms Categories
Random term
Thermochemistry & Thermodynamics

Free Energy and Equilibrium Constant

The relation connecting the standard Gibbs energy change of a reaction to its equilibrium constant.

Formula / equation ΔG° = −RT ln K
Unit kJ/mol

In depth

The equation converts a thermodynamic quantity into a measurable equilibrium position and back again. Because the relationship is logarithmic, a modest free energy change produces an enormous change in K: about 6 kJ/mol shifts K by a factor of ten at room temperature.

Examples in the real world

ΔG° = −40 kJ/mol corresponds to K ≈ 10⁷ at 298 K, meaning the reaction goes essentially to completion.