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Chemical Bonding & Molecular Structure

Sigma Bond

A covalent bond formed by the head-on overlap of atomic orbitals, with electron density concentrated along the internuclear axis.

kJ/mol
Foundations of Chemistry

Significant Figures

The digits in a measured value that carry meaningful precision, comprising all certain digits plus one estimated digit.

Dimensionless
States of Matter & Gas Laws

Simple Cubic

A crystal arrangement with particles only at the eight corners of a cubic unit cell.

1 atom per cell, 52% packing Dimensionless
Chemical Equilibrium

Simultaneous Equilibria

Several equilibria existing together in the same solution, all satisfied at once.

mol/L
Stoichiometry & Chemical Reactions

Single Displacement Reaction

A reaction in which a more reactive element replaces a less reactive one from its compound.

A + BC → AC + B Dimensionless
Inorganic & Coordination Chemistry

Slag

The molten by-product formed when a flux combines with the gangue during smelting.

Dimensionless
Stoichiometry & Chemical Reactions

Smelting

The reduction of a metal oxide to the metal by heating with a reducing agent, usually carbon or carbon monoxide.

MO + C → M + CO °C
Organic Chemistry

SN1 Reaction

A two-step nucleophilic substitution proceeding through a carbocation intermediate.

rate = k[substrate] s⁻¹
Organic Chemistry

SN2 Reaction

A single-step nucleophilic substitution in which bond formation and bond breaking occur simultaneously.

rate = k[substrate][nucleophile] L/(mol·s)
Solutions & Colligative Properties

Sol

A colloidal system consisting of solid particles dispersed throughout a liquid medium.

nm
States of Matter & Gas Laws

Solid State

The state of matter in which particles are held in fixed positions, giving a definite shape and volume.

Dimensionless
Solutions & Colligative Properties

Solubility

The maximum quantity of a solute that dissolves in a given amount of solvent at a specified temperature to give a saturated solution.

S = g solute / 100 g solvent g/100 g
Chemical Equilibrium

Solubility and Ksp Relationship

The mathematical link between molar solubility and the solubility product of a salt.

Ksp = n^n m^m s^(m+n) mol/L
Solutions & Colligative Properties

Solubility of Gases

The amount of a gas that dissolves in a given volume of liquid at a stated temperature and partial pressure.

S ∝ p, S decreases with T mol/L
Chemical Equilibrium

Solubility Product

The equilibrium constant for the dissolution of a sparingly soluble ionic solid into its constituent ions.

Ksp = [A⁺]^m[B⁻]^n Various
Stoichiometry & Chemical Reactions

Solubility Rules

A set of empirical guidelines predicting whether an ionic compound will dissolve appreciably in water.

Dimensionless
Solutions & Colligative Properties

Solute

The component of a solution present in the smaller amount, which is dispersed throughout the solvent.

mol
Solutions & Colligative Properties

Solution

A homogeneous mixture in which one or more substances are dispersed uniformly at the molecular or ionic level in another.

Dimensionless
Solutions & Colligative Properties

Solvation

The surrounding and stabilisation of a solute particle by a shell of solvent molecules.

kJ/mol
Solutions & Colligative Properties

Solvent

The component of a solution present in the greater amount, which dissolves and disperses the solute.

L
Chemical Equilibrium

Solvent Extraction Equilibrium

The equilibrium established when a solute is transferred between two immiscible liquid phases in a separating funnel.

efficiency = P V₁ / (P V₁ + V₂) Dimensionless
Chemical Bonding & Molecular Structure

sp Hybridisation

The mixing of one s and one p orbital to give two linear hybrid orbitals at 180° to each other.

2 hybrids, 180° degrees
Thermochemistry & Thermodynamics

Specific Heat Capacity

The heat required to raise the temperature of one kilogram of a substance by one kelvin.

c = q / (mΔT) J/(kg·K)
Analytical Chemistry & Spectroscopy

Specificity

The ability of a method to measure the analyte accurately in the presence of everything else in the sample.

Dimensionless