Home Wikituition Browse all terms Categories
Random term

Results for “pH”

291 terms · page 3 of 13


A–Z
All A B C D E F G H I J K L M N O P Q R S T U V W X Y Z
Filtering by: pH Clear all
Acids, Bases & Salts

Buffer Range

The span of pH values over which a buffer works effectively, conventionally one unit either side of its pKa.

pH = pKa ± 1 Dimensionless
Acids, Bases & Salts

Buffer Solution

A solution that resists changes in pH when small amounts of acid or base are added.

Dimensionless
Thermochemistry & Thermodynamics

Calorimetry

The experimental measurement of heat exchanged during a physical or chemical change.

q = mcΔT J
Organic Chemistry

Cannizzaro Reaction

The disproportionation of an aldehyde with no alpha hydrogen under concentrated alkali into an alcohol and a carboxylate.

2RCHO + OH⁻ → RCH₂OH + RCOO⁻ Dimensionless
Electrochemistry & Redox

Cell Notation

A shorthand convention for representing an electrochemical cell using vertical lines for phase boundaries.

Zn(s) | Zn²⁺(aq) ‖ Cu²⁺(aq) | Cu(s) Dimensionless
Inorganic & Coordination Chemistry

Counter Ion

An ion outside the coordination sphere that balances the charge of the complex ion.

Dimensionless
States of Matter & Gas Laws

Critical Point

The unique combination of temperature and pressure at which the liquid and gas phases of a substance become indistinguishable.

(T_c, p_c) K, Pa
States of Matter & Gas Laws

Deposition

The direct conversion of a vapour into a solid without an intermediate liquid phase.

kJ/mol
States of Matter & Gas Laws

Evaporation

The escape of molecules from the surface of a liquid into the vapour phase below the boiling point.

kJ/mol
Electrochemistry & Redox

Glass Electrode

An ion-selective electrode whose thin glass membrane develops a potential proportional to the pH of the solution.

E = constant − 0.0592 pH V
Organic Chemistry

Grignard Reagent

An organomagnesium halide that acts as a source of a carbanion-like nucleophilic carbon.

R–Mg–X Dimensionless
Acids, Bases & Salts

Henderson–Hasselbalch Equation

The equation giving the pH of a buffer from the pKa of its acid and the ratio of conjugate base to acid.

pH = pKa + log([A⁻]/[HA]) Dimensionless
Chemical Kinetics & Catalysis

Heterogeneous Catalysis

Catalysis in which the catalyst is in a different phase from the reactants, usually a solid with gaseous or liquid reagents.

Dimensionless
Chemical Equilibrium

Heterogeneous Equilibrium

An equilibrium involving species present in more than one phase.

Dimensionless
Foundations of Chemistry

Heterogeneous Mixture

A mixture in which the components remain physically distinct, so composition varies from one region of the sample to another.

Dimensionless
States of Matter & Gas Laws

Hexagonal Close Packing

A close-packed arrangement in which layers of spheres repeat in an ABAB sequence.

6 atoms per cell, 74% packing Dimensionless
Chemical Kinetics & Catalysis

Homogeneous Catalysis

Catalysis in which the catalyst is in the same phase as the reactants.

Dimensionless
Chemical Equilibrium

Homogeneous Equilibrium

An equilibrium in which all the reacting species are present in the same phase.

Dimensionless
Inorganic & Coordination Chemistry

Hydrate Isomerism

Isomerism arising from water molecules occupying either the coordination sphere or lattice positions outside it.

Dimensionless
Acids, Bases & Salts

Indicator Range

The span of pH over which an indicator's colour visibly changes, roughly one unit either side of its pKa.

pH = pK_In ± 1 Dimensionless
States of Matter & Gas Laws

Interstitial Void

An empty space between the packed spheres of a crystal lattice, capable of hosting a smaller ion or atom.

r_void / r_sphere = 0.225 or 0.414 Dimensionless
Inorganic & Coordination Chemistry

Ionisation Isomerism

Isomerism arising when an anion inside the coordination sphere exchanges places with the counter ion outside it.

Dimensionless
Biochemistry & Polymer Chemistry

Isoelectric Point

The pH at which a molecule carries no net electrical charge.

pI = (pKa₁ + pKa₂)/2 Dimensionless
Electrochemistry & Redox

Lithium-Ion Battery

A rechargeable cell in which lithium ions shuttle between a graphite anode and a metal oxide cathode.

LiCoO₂ + C₆ ⇌ Li₁₋ₓCoO₂ + LiₓC₆ V