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Thermochemistry & Thermodynamics

Calorimetry

The experimental measurement of heat exchanged during a physical or chemical change.

Formula / equation q = mcΔT
Unit J

In depth

A calorimeter isolates the reaction thermally so that the heat released or absorbed can be inferred from the temperature change of a known mass of surrounding material. Corrections for the calorimeter's own heat capacity and for heat leakage are essential for accurate results.

Examples in the real world

Using a polystyrene cup calorimeter for a neutralisation reaction, and a bomb calorimeter for combustion.