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States of Matter & Gas Laws

Critical Point

The unique combination of temperature and pressure at which the liquid and gas phases of a substance become indistinguishable.

Formula / equation (T_c, p_c)
Unit K, Pa

In depth

At this point the densities of liquid and vapour converge, the meniscus vanishes and surface tension falls to zero. The phenomenon of critical opalescence — intense light scattering from density fluctuations — makes the transition visible. Beyond it lies the supercritical region.

Examples in the real world

Water's critical point is 374 °C and 218 atm; carbon dioxide's is a far more accessible 31 °C and 73 atm.