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Chemical Kinetics & Catalysis

Reaction Rate

The change in concentration of a reactant or product per unit time.

rate = −Δ[A]/(aΔt) = Δ[P]/(pΔt) mol/(L·s)
Foundations of Chemistry

Reagent

A substance added to a system to bring about a chemical reaction or to test for the presence of another substance.

Dimensionless
States of Matter & Gas Laws

Real Gas

An actual gas whose behaviour deviates from the ideal gas law because its molecules occupy volume and attract one another.

Z = pV / nRT ≠ 1 Dimensionless
Stoichiometry & Chemical Reactions

Rearrangement Reaction

A reaction in which the atoms of a molecule are reorganised to give a structural isomer.

A → A′ (isomer) Dimensionless
Electrochemistry & Redox

Redox Couple

The oxidised and reduced forms of the same species, considered together as a conjugate pair.

Ox / Red V
Stoichiometry & Chemical Reactions

Redox Reaction

A reaction in which electrons are transferred, so that one species is oxidised while another is reduced.

Ox₁ + Red₂ → Red₁ + Ox₂ V
Analytical Chemistry & Spectroscopy

Redox Titration

A titration in which the reaction between titrant and analyte involves electron transfer.

mol/L
Electrochemistry & Redox

Reducing Agent

A species that donates electrons to another substance and is itself oxidised in the process.

V
Biochemistry & Polymer Chemistry

Reducing Sugar

A sugar with a free aldehyde or ketone group that can reduce mild oxidising agents.

Dimensionless
Electrochemistry & Redox

Reduction

The gain of electrons by a species, accompanied by a decrease in its oxidation number.

Xⁿ⁺ + n e⁻ → X Dimensionless
Electrochemistry & Redox

Reference Electrode

A half-cell with a stable, known and reproducible potential, used as a fixed point against which other potentials are measured.

V
Chemical Equilibrium

Relationship between K and Rate Constants

The equilibrium constant of an elementary reaction equals the ratio of its forward and reverse rate constants.

K = k_forward / k_reverse Various
Acids, Bases & Salts

Relationship between Ka and Kb

The reciprocal link between the strengths of an acid and its conjugate base.

Ka × Kb = Kw Dimensionless
Chemical Equilibrium

Relationship between Kp and Kc

The conversion linking the pressure and concentration forms of the equilibrium constant for a gaseous reaction.

Kp = Kc(RT)^Δn Dimensionless
Foundations of Chemistry

Relative Atomic Mass

The weighted average mass of the atoms of an element, expressed relative to one twelfth the mass of a carbon-12 atom.

A_r = Σ(isotope abundance × isotope mass) Dimensionless
Solutions & Colligative Properties

Relative Lowering of Vapour Pressure

The fractional reduction in a solvent's vapour pressure caused by dissolving a non-volatile solute.

(p° − p) / p° = x_solute Dimensionless
Chemical Bonding & Molecular Structure

Resonance

The description of a molecule whose true structure is a weighted average of two or more valid Lewis structures.

A ↔ B ↔ C Dimensionless
Organic Chemistry

Resonance Effect

The delocalisation of pi or lone pair electrons through a conjugated system, altering electron density at distant atoms.

−M and +M effects Dimensionless
Chemical Bonding & Molecular Structure

Resonance Energy

The extra stability a molecule gains from electron delocalisation, measured against the most stable single Lewis structure.

ΔE_res = E(hybrid) − E(best structure) kJ/mol
Analytical Chemistry & Spectroscopy

Retention Factor

The ratio of the distance travelled by a component to the distance travelled by the solvent front.

Rf = d_spot / d_solvent Dimensionless
Solutions & Colligative Properties

Reverse Osmosis

The forced flow of solvent from a concentrated to a dilute solution by applying pressure greater than the osmotic pressure.

p_applied > π atm
Thermochemistry & Thermodynamics

Reversible Process

An idealised process carried out through a continuous series of equilibrium states, so it can be reversed by an infinitesimal change.

w_rev = −∫p dV J
Stoichiometry & Chemical Reactions

Reversible Reaction

A reaction that can proceed in both the forward and reverse directions under the same conditions.

A + B ⇌ C + D Dimensionless
Biochemistry & Polymer Chemistry

RNA

A generally single-stranded nucleic acid that carries out the expression of genetic information.

Dimensionless