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Foundations of Chemistry

Relative Atomic Mass

The weighted average mass of the atoms of an element, expressed relative to one twelfth the mass of a carbon-12 atom.

Formula / equation A_r = Σ(isotope abundance × isotope mass)
Unit Dimensionless

In depth

Because elements occur as isotopic mixtures, the value on the periodic table is an abundance-weighted average, not the mass of any single atom. This is why chlorine is quoted as 35.45 rather than 35 or 37. Values are revised periodically by IUPAC as isotopic measurements improve.

Examples in the real world

Chlorine is 75.8% ³⁵Cl and 24.2% ³⁷Cl, giving A_r = 0.758 × 35 + 0.242 × 37 ≈ 35.45.