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Thermochemistry & Thermodynamics

Reversible Process

An idealised process carried out through a continuous series of equilibrium states, so it can be reversed by an infinitesimal change.

Formula / equation w_rev = −∫p dV
Unit J

In depth

A reversible process is infinitely slow and leaves no net change in the universe when reversed, which is why it delivers the maximum possible work and creates no entropy. It is a theoretical limit rather than a practical procedure, but it provides the benchmark against which real processes are measured.

Examples in the real world

A gas expanding against a pressure lowered grain by grain; ice melting exactly at 0 °C.