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Thermochemistry & Thermodynamics

Path Function

A quantity whose value depends on the specific route taken between two states.

Formula / equation δq, δw
Unit J

In depth

Heat and work are the two path functions of thermodynamics: the same change of state can be brought about with different amounts of each. Only their sum, which equals the change in internal energy, is path-independent. Path functions are written with a small delta rather than a capital one.

Examples in the real world

An expanding gas doing maximum work along a reversible path but far less if it expands freely into a vacuum.