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Atomic Structure & Periodicity

Paramagnetism

Weak attraction into a magnetic field, shown by substances containing one or more unpaired electrons.

Formula / equation μ = √(n(n+2)) BM
Unit BM

In depth

Unpaired electron spins act as tiny magnetic dipoles that align with an applied field. The spin-only magnetic moment, measured in Bohr magnetons, gives the number of unpaired electrons directly, making magnetic measurement a standard way to determine the oxidation state and geometry of a transition-metal complex.

Examples in the real world

O₂ is drawn to a magnet because of two unpaired π* electrons; [Fe(H₂O)₆]³⁺ with five unpaired electrons gives μ ≈ 5.92 BM.