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Electrophile Organic Chemistry Dimensionless An electron-deficient species that seeks and accepts a pair of electrons from an electron-rich centre. E⁺ Electrophilic Addition Organic Chemistry Dimensionless A reaction in which an electrophile adds across a carbon–carbon multiple bond, converting a pi bond into two sigma bonds. C=C + E–Nu → C(E)–C(Nu) Electrophilic Substitution Organic Chemistry Dimensionless A reaction in which an electrophile replaces a hydrogen atom on an aromatic ring. ArH + E⁺ → ArE + H⁺ Electrophoresis Analytical Chemistry & Spectroscopy cm/s A separation technique in which charged species migrate through a medium under an applied electric field. v = μE Evaporation States of Matter & Gas Laws kJ/mol The escape of molecules from the surface of a liquid into the vapour phase below the boiling point. E1 Reaction Organic Chemistry s⁻¹ A two-step elimination proceeding through a carbocation, which then loses a proton to form an alkene. rate = k[substrate] Ebullioscopic Constant Solutions & Colligative Properties K·kg/mol The boiling point elevation produced by a one-molal solution of a non-electrolyte in a given solvent. K_b = RT_b²M / ΔH_vap Electrode Electrochemistry & Redox Dimensionless A conductor through which electric current enters or leaves an electrolyte. Electrolyte Electrochemistry & Redox S/m A substance that produces mobile ions when dissolved or molten and therefore conducts electricity. Emulsion Solutions & Colligative Properties nm A colloidal dispersion of one liquid as fine droplets throughout another liquid with which it is immiscible. Enantiomer Organic Chemistry degrees One of a pair of stereoisomers that are non-superimposable mirror images of each other. (+) and (−), or R and S Endergonic Reaction Thermochemistry & Thermodynamics kJ/mol A reaction with a positive Gibbs free energy change, which requires an input of energy to proceed. ΔG > 0 Enthalpy Thermochemistry & Thermodynamics kJ/mol A thermodynamic state function equal to internal energy plus the product of pressure and volume. H = U + pV Enthalpy of Sublimation Thermochemistry & Thermodynamics kJ/mol The enthalpy change when one mole of a solid converts directly into vapour. ΔH_sub = ΔH_fus + ΔH_vap Enzyme Biochemistry & Polymer Chemistry Dimensionless A biological catalyst, almost always a protein, that accelerates a specific biochemical reaction. Enzyme Catalysis Chemical Kinetics & Catalysis Dimensionless Catalysis by protein molecules that bind substrates at a specific active site and lower the activation energy dramatically. Equivalence Point Acids, Bases & Salts mol The point in a titration at which exactly stoichiometric amounts of the two reactants have been combined. n_acid × basicity = n_base × acidity Element Foundations of Chemistry Dimensionless A pure substance composed entirely of atoms that share the same atomic number and therefore cannot be split into simpler substances by chemical means. End Point Acids, Bases & Salts mL The point in a titration at which the indicator changes colour, signalling that the reaction is judged complete. Endothermic Reaction Stoichiometry & Chemical Reactions kJ/mol A reaction that absorbs energy from the surroundings, giving a positive enthalpy change. ΔH > 0