Results for “pH”
20 terms
Electrophile
Organic Chemistry
Dimensionless
An electron-deficient species that seeks and accepts a pair of electrons from an electron-rich centre.
E⁺
Electrophilic Addition
Organic Chemistry
Dimensionless
A reaction in which an electrophile adds across a carbon–carbon multiple bond, converting a pi bond into two sigma bonds.
C=C + E–Nu → C(E)–C(Nu)
Electrophilic Substitution
Organic Chemistry
Dimensionless
A reaction in which an electrophile replaces a hydrogen atom on an aromatic ring.
ArH + E⁺ → ArE + H⁺
Electrophoresis
Analytical Chemistry & Spectroscopy
cm/s
A separation technique in which charged species migrate through a medium under an applied electric field.
v = μE
Evaporation
States of Matter & Gas Laws
kJ/mol
The escape of molecules from the surface of a liquid into the vapour phase below the boiling point.
E1 Reaction
Organic Chemistry
s⁻¹
A two-step elimination proceeding through a carbocation, which then loses a proton to form an alkene.
rate = k[substrate]
Ebullioscopic Constant
Solutions & Colligative Properties
K·kg/mol
The boiling point elevation produced by a one-molal solution of a non-electrolyte in a given solvent.
K_b = RT_b²M / ΔH_vap
Electrode
Electrochemistry & Redox
Dimensionless
A conductor through which electric current enters or leaves an electrolyte.
Electrolyte
Electrochemistry & Redox
S/m
A substance that produces mobile ions when dissolved or molten and therefore conducts electricity.
Emulsion
Solutions & Colligative Properties
nm
A colloidal dispersion of one liquid as fine droplets throughout another liquid with which it is immiscible.
Enantiomer
Organic Chemistry
degrees
One of a pair of stereoisomers that are non-superimposable mirror images of each other.
(+) and (−), or R and S
Endergonic Reaction
Thermochemistry & Thermodynamics
kJ/mol
A reaction with a positive Gibbs free energy change, which requires an input of energy to proceed.
ΔG > 0
Enthalpy
Thermochemistry & Thermodynamics
kJ/mol
A thermodynamic state function equal to internal energy plus the product of pressure and volume.
H = U + pV
Enthalpy of Sublimation
Thermochemistry & Thermodynamics
kJ/mol
The enthalpy change when one mole of a solid converts directly into vapour.
ΔH_sub = ΔH_fus + ΔH_vap
Enzyme
Biochemistry & Polymer Chemistry
Dimensionless
A biological catalyst, almost always a protein, that accelerates a specific biochemical reaction.
Enzyme Catalysis
Chemical Kinetics & Catalysis
Dimensionless
Catalysis by protein molecules that bind substrates at a specific active site and lower the activation energy dramatically.
Equivalence Point
Acids, Bases & Salts
mol
The point in a titration at which exactly stoichiometric amounts of the two reactants have been combined.
n_acid × basicity = n_base × acidity
Element
Foundations of Chemistry
Dimensionless
A pure substance composed entirely of atoms that share the same atomic number and therefore cannot be split into simpler substances by chemical means.
End Point
Acids, Bases & Salts
mL
The point in a titration at which the indicator changes colour, signalling that the reaction is judged complete.
Endothermic Reaction
Stoichiometry & Chemical Reactions
kJ/mol
A reaction that absorbs energy from the surroundings, giving a positive enthalpy change.
ΔH > 0