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Chemical Kinetics & Catalysis

Enzyme Catalysis

Catalysis by protein molecules that bind substrates at a specific active site and lower the activation energy dramatically.

Unit Dimensionless

In depth

Enzymes achieve rate enhancements of up to 10¹⁷ and are exquisitely selective, often for a single substrate and a single stereochemical outcome. They work under mild conditions of temperature and pH but are denatured outside a narrow range, and are regulated by inhibitors and activators.

Examples in the real world

Catalase decomposing hydrogen peroxide at millions of molecules per second; amylase hydrolysing starch.