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Thermochemistry & Thermodynamics

Enthalpy

A thermodynamic state function equal to internal energy plus the product of pressure and volume.

Formula / equation H = U + pV
Unit kJ/mol

In depth

Enthalpy was defined so that, at constant pressure, its change equals the heat exchanged — exactly the condition of an open beaker. This makes it the natural energy quantity for chemistry, since almost all laboratory reactions occur under atmospheric pressure.

Examples in the real world

The 890 kJ/mol released when methane burns is an enthalpy change measured at constant pressure.