Home Wikituition Browse all terms Categories
Random term
Organic Chemistry

Electrophile

An electron-deficient species that seeks and accepts a pair of electrons from an electron-rich centre.

Formula / equation E⁺
Unit Dimensionless

In depth

Electrophiles are Lewis acids and may be positively charged or simply have an atom with an incomplete octet or a strong partial positive charge. They attack the electron-rich regions of molecules, especially pi bonds and lone pairs.

Examples in the real world

NO₂⁺ in nitration, Br⁺ in bromination, and the carbonyl carbon of an aldehyde.