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States of Matter & Gas Laws

Condensation

The change of a substance from the gaseous to the liquid state, accompanied by the release of latent heat.

kJ/mol
Biochemistry & Polymer Chemistry

Condensation Polymerisation

Polymerisation in which monomers join with the elimination of a small molecule, usually water.

n A + n B → –(AB)ₙ– + n H₂O Dimensionless
Stoichiometry & Chemical Reactions

Condensation Reaction

A reaction in which two molecules join with the elimination of a small molecule, usually water.

A–OH + H–B → A–B + H₂O Dimensionless
Electrochemistry & Redox

Conductometric Titration

A titration in which the end point is found from changes in the conductivity of the solution.

S/m
Analytical Chemistry & Spectroscopy

Confidence Interval

The range within which the true value of a measured quantity is expected to lie with a stated probability.

μ = x̄ ± ts / √n Various
Organic Chemistry

Conformational Isomerism

The different spatial arrangements a molecule can adopt through rotation about single bonds.

kJ/mol
Acids, Bases & Salts

Conjugate Acid–Base Pair

Two species differing by exactly one proton, one being the acid and the other its corresponding base.

HA / A⁻ Dimensionless
Nuclear & Radiochemistry

Control Rod

A movable rod of neutron-absorbing material used to regulate the rate of a nuclear chain reaction.

Dimensionless
Chemical Bonding & Molecular Structure

Coordinate Bond

A covalent bond in which both shared electrons are supplied by the same atom.

A: + B → A→B kJ/mol
Inorganic & Coordination Chemistry

Coordination Compound

A compound containing a central metal atom or ion bonded to surrounding molecules or ions by coordinate bonds.

[M(L)ₙ]Xₘ Dimensionless
Inorganic & Coordination Chemistry

Coordination Isomerism

Isomerism in compounds containing both a complex cation and a complex anion, where ligands are distributed differently between them.

Dimensionless
Chemical Bonding & Molecular Structure

Coordination Number

The number of nearest neighbours immediately surrounding a given atom or ion in a lattice or complex.

Dimensionless
Inorganic & Coordination Chemistry

Coordination Sphere

The central metal together with the ligands directly attached to it, written inside square brackets.

[M(L)ₙ] Dimensionless
Biochemistry & Polymer Chemistry

Copolymer

A polymer made from two or more different monomers.

Dimensionless
Atomic Structure & Periodicity

Core Electron

An electron occupying a completely filled inner shell that does not take part in chemical bonding.

Dimensionless
Electrochemistry & Redox

Corrosion

The gradual destruction of a metal by electrochemical reaction with its environment.

mm/year
Inorganic & Coordination Chemistry

Counter Ion

An ion outside the coordination sphere that balances the charge of the complex ion.

Dimensionless
Chemical Equilibrium

Coupled Equilibria

Two or more equilibria that share a common species, so that shifting one necessarily shifts the others.

Dimensionless
Thermochemistry & Thermodynamics

Coupled Reactions

Two reactions linked through a shared intermediate so that a favourable one drives an unfavourable one.

ΔG_total = ΔG₁ + ΔG₂ < 0 kJ/mol
Chemical Bonding & Molecular Structure

Covalent Bond

A bond formed when two atoms share one or more pairs of electrons so that both achieve a stable configuration.

A· + ·B → A:B kJ/mol
Nuclear & Radiochemistry

Critical Mass

The minimum mass of fissile material needed to sustain a nuclear chain reaction.

kg
States of Matter & Gas Laws

Critical Point

The unique combination of temperature and pressure at which the liquid and gas phases of a substance become indistinguishable.

(T_c, p_c) K, Pa
States of Matter & Gas Laws

Critical Temperature

The temperature above which a gas cannot be liquefied by pressure alone, however great.

T_c = 8a / 27Rb K
Biochemistry & Polymer Chemistry

Cross-Linking

The formation of covalent bonds between separate polymer chains.

Dimensionless