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Chemical Equilibrium

Chemical Equilibrium

The state of a reversible reaction in which the forward and reverse reactions proceed at equal rates, so no net change in composition occurs.

Formula / equation aA + bB ⇌ cC + dD
Unit Dimensionless

In depth

Equilibrium is reached only in a closed system and can be approached from either direction, arriving at the same composition. Concentrations remain constant but are not necessarily equal, and the reaction has not stopped — it has merely become balanced. At equilibrium the Gibbs energy of the system is at a minimum.

Examples in the real world

N₂ + 3H₂ ⇌ 2NH₃ in a sealed reactor settling to a fixed mixture of all three gases.