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Chemical Equilibrium

Magnitude of K and Extent of Reaction

The use of the size of the equilibrium constant to judge how far a reaction proceeds before equilibrium is reached.

Formula / equation K ≫ 1: products favoured
Unit Dimensionless

In depth

A constant above about 10³ means the reaction is effectively complete, one below 10⁻³ means it barely proceeds, and intermediate values mean appreciable amounts of everything are present at equilibrium. The magnitude says nothing whatever about how quickly that state is reached.

Examples in the real world

The combustion of methane has K near 10¹⁴⁰ and goes to completion; N₂ + O₂ ⇌ 2NO has K ≈ 10⁻³⁰ at room temperature.