Home Wikituition Browse all terms Categories
Random term
Chemical Equilibrium

Common Ion Effect

The suppression of the ionisation or dissolution of a substance by adding a second substance that supplies one of the same ions.

Unit mol/L

In depth

The added ion increases the ionic product, so by Le Chatelier's principle the equilibrium shifts back towards the undissociated or undissolved form. The effect is the basis of buffer action and is exploited to complete precipitations by washing with a solution containing a common ion.

Examples in the real world

Adding concentrated HCl to saturated NaCl solution precipitates salt; adding acetate ion suppresses acetic acid ionisation.