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Product Stoichiometry & Chemical Reactions mol A substance formed as a result of a chemical reaction. Promoter Chemical Kinetics & Catalysis Dimensionless A substance that has little catalytic activity itself but greatly increases the effectiveness of a catalyst. Protein Biochemistry & Polymer Chemistry g/mol A large biomolecule made of one or more chains of amino acids folded into a specific three-dimensional shape. Proton Atomic Structure & Periodicity u A positively charged subatomic particle found in the atomic nucleus, carrying a charge of +1 elementary unit. m_p = 1.6726 × 10⁻²⁷ kg Proton Affinity Acids, Bases & Salts kJ/mol The energy released when a gaseous species accepts a proton, measuring intrinsic basicity free of solvent effects. B(g) + H⁺(g) → BH⁺(g) Pseudo-First-Order Reaction Chemical Kinetics & Catalysis s⁻¹ A higher-order reaction that behaves as first order because one reactant is present in such large excess that its concentration is effectively constant. rate = k′[A], k′ = k[B]₀ Pure Substance Foundations of Chemistry Dimensionless Matter with a fixed chemical composition and a definite set of physical properties, comprising either a single element or a single compound. Purity Foundations of Chemistry Dimensionless The mass fraction of the desired substance in a sample, usually expressed as a percentage of the total mass. purity % = (mass of pure substance / total mass) × 100 Pyrolysis Stoichiometry & Chemical Reactions °C The thermal decomposition of a substance at high temperature in the absence of oxygen. complex → simpler fragments (Δ, no O₂) Qualitative Analysis Analytical Chemistry & Spectroscopy Dimensionless Analysis carried out to establish which species are present in a sample. Quantitative Analysis Analytical Chemistry & Spectroscopy Various Analysis carried out to determine the amount or concentration of a species in a sample. Quantum Mechanical Model Atomic Structure & Periodicity Dimensionless The modern description of the atom in which electrons are represented by wavefunctions giving probability distributions rather than definite paths. Ĥψ = Eψ Quaternary Structure Biochemistry & Polymer Chemistry Dimensionless The arrangement of two or more folded polypeptide chains into a functional protein complex. Racemic Mixture Organic Chemistry degrees An equimolar mixture of two enantiomers, which shows no net optical rotation. 50:50 (+) and (−) Radiation Dose Nuclear & Radiochemistry Gy A measure of the energy deposited in matter by ionising radiation. D = E / m Radioactive Activity Nuclear & Radiochemistry Bq The number of nuclear disintegrations occurring in a sample per unit time. A = λN Radioactive Decay Series Nuclear & Radiochemistry Dimensionless A sequence of successive radioactive decays leading from a long-lived parent to a stable end product. Radioactive Half-Life Nuclear & Radiochemistry s The time required for half the nuclei in a radioactive sample to decay. t½ = 0.693 / λ Radioactive Tracer Nuclear & Radiochemistry Bq A radioisotope introduced into a system so that its pathway can be followed by detecting its radiation. Radioactive Waste Nuclear & Radiochemistry Bq/kg Material containing radionuclides for which no further use is foreseen and which requires controlled disposal. Radioactivity Nuclear & Radiochemistry Bq The spontaneous emission of particles or electromagnetic radiation from unstable atomic nuclei. Radiocarbon Dating Nuclear & Radiochemistry years A dating technique that determines the age of organic material from its residual carbon-14 content. t = (t½ / 0.693) ln(N₀/N) Radioisotope Nuclear & Radiochemistry Dimensionless An isotope of an element whose nucleus is unstable and undergoes radioactive decay. Radiolysis Nuclear & Radiochemistry Dimensionless The chemical decomposition of a substance caused by ionising radiation. H₂O →(radiation) H· + OH·