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Stoichiometry & Chemical Reactions

Pyrolysis

The thermal decomposition of a substance at high temperature in the absence of oxygen.

Formula / equation complex → simpler fragments (Δ, no O₂)
Unit °C

In depth

Without oxygen the material cannot burn, so instead its bonds fracture into smaller molecules, gases and a carbon-rich char. Pyrolysis of long-chain hydrocarbons, called cracking, converts surplus heavy fractions into petrol and alkene feedstocks for the polymer industry.

Examples in the real world

Cracking decane into octane and ethene; converting wood into charcoal; producing bio-oil from agricultural waste.