Results for “pH”
291 terms · page 2 of 13
Electrophilic Addition
Organic Chemistry
Dimensionless
A reaction in which an electrophile adds across a carbon–carbon multiple bond, converting a pi bond into two sigma bonds.
C=C + E–Nu → C(E)–C(Nu)
Electrophilic Substitution
Organic Chemistry
Dimensionless
A reaction in which an electrophile replaces a hydrogen atom on an aromatic ring.
ArH + E⁺ → ArE + H⁺
Electrophoresis
Analytical Chemistry & Spectroscopy
cm/s
A separation technique in which charged species migrate through a medium under an applied electric field.
v = μE
Gas Chromatography
Analytical Chemistry & Spectroscopy
min
A technique for separating volatile compounds carried by an inert gas through a heated column.
Gas Chromatography–Mass Spectrometry
Analytical Chemistry & Spectroscopy
Dimensionless
A hybrid technique in which compounds separated by gas chromatography are identified by a mass spectrometer.
High-Performance Liquid Chromatography
Analytical Chemistry & Spectroscopy
min
A technique in which a liquid mobile phase is pumped at high pressure through a column of very fine stationary phase.
Isomorphism
States of Matter & Gas Laws
Dimensionless
The property of two or more different substances crystallising in the same structural form.
Mobile Phase
Analytical Chemistry & Spectroscopy
mL/min
The fluid that carries the sample through the stationary phase during chromatography.
Nucleophile
Organic Chemistry
Dimensionless
An electron-rich species that donates a pair of electrons to form a new covalent bond.
Nu⁻ or Nu:
Nucleophilic Substitution
Organic Chemistry
Dimensionless
A reaction in which a nucleophile replaces a leaving group attached to a saturated carbon.
Nu⁻ + R–X → R–Nu + X⁻
Polymorphism
States of Matter & Gas Laws
Dimensionless
The ability of a single substance to exist in more than one crystalline form.
Radiopharmaceutical
Nuclear & Radiochemistry
MBq
A radioactive compound administered to a patient for diagnosis or treatment.
Stationary Phase
Analytical Chemistry & Spectroscopy
Dimensionless
The fixed material in a chromatographic system with which the sample components interact as they pass.
Thin Layer Chromatography
Analytical Chemistry & Spectroscopy
Dimensionless
A chromatographic technique using a thin layer of adsorbent coated on a flat plate.
X-ray Crystallography
Analytical Chemistry & Spectroscopy
pm
A technique that determines the three-dimensional atomic structure of a crystal from its X-ray diffraction pattern.
nλ = 2d sin θ
Acidic Buffer
Acids, Bases & Salts
Dimensionless
A buffer made from a weak acid and one of its salts, giving a pH below 7.
pH = pKa + log([salt]/[acid])
Acidic Salt
Acids, Bases & Salts
Dimensionless
A salt whose aqueous solution has a pH below 7, or one that still contains replaceable hydrogen.
Acid–Base Titration
Acids, Bases & Salts
mol/L
A titration in which an acid is neutralised by a base, or the reverse, monitored by an indicator or a pH meter.
M_aV_a / n_a = M_bV_b / n_b
Allotropy
Foundations of Chemistry
Dimensionless
The existence of an element in two or more distinct structural forms within the same physical state.
Anisotropy
States of Matter & Gas Laws
Dimensionless
The dependence of a physical property on the direction in which it is measured.
Basic Buffer
Acids, Bases & Salts
Dimensionless
A buffer made from a weak base and one of its salts, giving a pH above 7.
pOH = pKb + log([salt]/[base])
Basic Salt
Acids, Bases & Salts
Dimensionless
A salt whose aqueous solution has a pH above 7, or one that retains a hydroxide group.
Bond Dissociation Enthalpy
Thermochemistry & Thermodynamics
kJ/mol
The enthalpy change when one mole of a specific bond is broken homolytically in the gas phase.
A–B(g) → A·(g) + B·(g)
Buffer Capacity
Acids, Bases & Salts
mol/L
The amount of strong acid or base a buffer can absorb before its pH changes appreciably.
β = dn / d(pH)