Terms starting with V
17 terms
Valence Bond Theory
Chemical Bonding & Molecular Structure
Dimensionless
The bonding model in which a covalent bond forms by the overlap of half-filled atomic orbitals on adjacent atoms.
Valence Bond Theory of Complexes
Inorganic & Coordination Chemistry
Dimensionless
The model describing coordinate bonding as the overlap of filled ligand orbitals with hybridised empty orbitals on the metal.
d²sp³, sp³d², sp³, dsp²
Valence Electron
Atomic Structure & Periodicity
Dimensionless
An electron in the outermost occupied shell of an atom, available for bonding.
Valency
Foundations of Chemistry
Dimensionless
The combining capacity of an element, equal to the number of electrons an atom gains, loses or shares when forming compounds.
Van Arkel Process
Inorganic & Coordination Chemistry
°C
A purification method in which a metal is converted to a volatile iodide and then decomposed on a hot filament.
Ti + 2I₂ ⇌ TiI₄
Van der Waals Equation
States of Matter & Gas Laws
Various
A modified equation of state that corrects the ideal gas law for molecular volume and intermolecular attraction.
(p + an²/V²)(V − nb) = nRT
Van der Waals Forces
Chemical Bonding & Molecular Structure
kJ/mol
The collective name for the weak attractive forces between molecules arising from dipole interactions.
E ∝ 1 / r⁶
Van't Hoff Equation
Chemical Equilibrium
kJ/mol
The equation describing how an equilibrium constant varies with temperature.
ln(K₂/K₁) = −ΔH°/R (1/T₂ − 1/T₁)
Van't Hoff Factor
Solutions & Colligative Properties
Dimensionless
The ratio of the actual number of particles produced in solution to the number of formula units dissolved.
i = observed ΔT / calculated ΔT
Vapour Pressure
States of Matter & Gas Laws
Pa
The pressure exerted by a vapour in dynamic equilibrium with its liquid or solid at a given temperature.
ln p = −ΔH_vap / RT + C
Vapour–Liquid Equilibrium
Chemical Equilibrium
Pa
The equilibrium between a liquid and its vapour in a closed container at a given temperature.
p = p_saturated
Viscosity
States of Matter & Gas Laws
Pa·s
A liquid's resistance to flow, arising from internal friction between adjacent layers of molecules.
F = ηA (dv/dx)
Vitamin
Biochemistry & Polymer Chemistry
mg
An organic compound required in small amounts that an organism cannot synthesise for itself.
Volume Percentage
Solutions & Colligative Properties
Dimensionless
The volume of a liquid solute expressed as a percentage of the total volume of solution.
% v/v = (V_solute / V_solution) × 100
Volumetric Analysis
Analytical Chemistry & Spectroscopy
mL
Quantitative analysis based on measuring the volume of a standard solution needed to react with the analyte.
n = M × V
VSEPR Theory
Chemical Bonding & Molecular Structure
Dimensionless
The model that predicts molecular shape by arranging valence electron pairs around a central atom so their mutual repulsion is minimised.
AXₘEₙ notation
Vulcanisation
Biochemistry & Polymer Chemistry
Dimensionless
The treatment of natural rubber with sulfur to form cross-links that greatly improve its properties.