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Atomic Structure & Periodicity

Valence Electron

An electron in the outermost occupied shell of an atom, available for bonding.

Unit Dimensionless

In depth

Valence electrons determine an element's group, valency, bonding capacity and most of its chemistry. For main-group elements their number equals the group number modulo ten; for transition metals, d-electrons in the penultimate shell also participate, which is why variable oxidation states are common there.

Examples in the real world

Sodium has one valence electron (3s¹); chlorine has seven (3s² 3p⁵); carbon has four.