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Terms starting with V

17 terms


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Chemical Bonding & Molecular Structure

Valence Bond Theory

The bonding model in which a covalent bond forms by the overlap of half-filled atomic orbitals on adjacent atoms.

Dimensionless
Inorganic & Coordination Chemistry

Valence Bond Theory of Complexes

The model describing coordinate bonding as the overlap of filled ligand orbitals with hybridised empty orbitals on the metal.

d²sp³, sp³d², sp³, dsp² Dimensionless
Atomic Structure & Periodicity

Valence Electron

An electron in the outermost occupied shell of an atom, available for bonding.

Dimensionless
Foundations of Chemistry

Valency

The combining capacity of an element, equal to the number of electrons an atom gains, loses or shares when forming compounds.

Dimensionless
Inorganic & Coordination Chemistry

Van Arkel Process

A purification method in which a metal is converted to a volatile iodide and then decomposed on a hot filament.

Ti + 2I₂ ⇌ TiI₄ °C
States of Matter & Gas Laws

Van der Waals Equation

A modified equation of state that corrects the ideal gas law for molecular volume and intermolecular attraction.

(p + an²/V²)(V − nb) = nRT Various
Chemical Bonding & Molecular Structure

Van der Waals Forces

The collective name for the weak attractive forces between molecules arising from dipole interactions.

E ∝ 1 / r⁶ kJ/mol
Chemical Equilibrium

Van't Hoff Equation

The equation describing how an equilibrium constant varies with temperature.

ln(K₂/K₁) = −ΔH°/R (1/T₂ − 1/T₁) kJ/mol
Solutions & Colligative Properties

Van't Hoff Factor

The ratio of the actual number of particles produced in solution to the number of formula units dissolved.

i = observed ΔT / calculated ΔT Dimensionless
States of Matter & Gas Laws

Vapour Pressure

The pressure exerted by a vapour in dynamic equilibrium with its liquid or solid at a given temperature.

ln p = −ΔH_vap / RT + C Pa
Chemical Equilibrium

Vapour–Liquid Equilibrium

The equilibrium between a liquid and its vapour in a closed container at a given temperature.

p = p_saturated Pa
States of Matter & Gas Laws

Viscosity

A liquid's resistance to flow, arising from internal friction between adjacent layers of molecules.

F = ηA (dv/dx) Pa·s
Biochemistry & Polymer Chemistry

Vitamin

An organic compound required in small amounts that an organism cannot synthesise for itself.

mg
Solutions & Colligative Properties

Volume Percentage

The volume of a liquid solute expressed as a percentage of the total volume of solution.

% v/v = (V_solute / V_solution) × 100 Dimensionless
Analytical Chemistry & Spectroscopy

Volumetric Analysis

Quantitative analysis based on measuring the volume of a standard solution needed to react with the analyte.

n = M × V mL
Chemical Bonding & Molecular Structure

VSEPR Theory

The model that predicts molecular shape by arranging valence electron pairs around a central atom so their mutual repulsion is minimised.

AXₘEₙ notation Dimensionless
Biochemistry & Polymer Chemistry

Vulcanisation

The treatment of natural rubber with sulfur to form cross-links that greatly improve its properties.

Dimensionless