Results for “pH”
39 terms · page 1 of 2
Stationary Phase
Analytical Chemistry & Spectroscopy
Dimensionless
The fixed material in a chromatographic system with which the sample components interact as they pass.
SN1 Reaction
Organic Chemistry
s⁻¹
A two-step nucleophilic substitution proceeding through a carbocation intermediate.
rate = k[substrate]
SN2 Reaction
Organic Chemistry
L/(mol·s)
A single-step nucleophilic substitution in which bond formation and bond breaking occur simultaneously.
rate = k[substrate][nucleophile]
Solvent Extraction Equilibrium
Chemical Equilibrium
Dimensionless
The equilibrium established when a solute is transferred between two immiscible liquid phases in a separating funnel.
efficiency = P V₁ / (P V₁ + V₂)
Supercritical Fluid
States of Matter & Gas Laws
K, Pa
A substance held above both its critical temperature and critical pressure, where liquid and gas phases are indistinguishable.
T > T_c and p > p_c
Salt
Acids, Bases & Salts
Dimensionless
An ionic compound formed when the hydrogen of an acid is replaced by a metal or other cation.
acid + base → salt + water
Salt Hydrolysis
Acids, Bases & Salts
mol/L
The reaction of a salt's ions with water to produce an acidic or alkaline solution.
A⁻ + H₂O ⇌ HA + OH⁻
Scintillation Counter
Nuclear & Radiochemistry
counts/s
A detector in which radiation causes a material to emit flashes of light that are counted and measured.
Second Law of Thermodynamics
Thermochemistry & Thermodynamics
J/K
The total entropy of the universe increases in every spontaneous process.
ΔS_universe > 0
Secondary Cell
Electrochemistry & Redox
V
A cell whose reaction can be reversed by an applied current, allowing it to be recharged and reused.
Secondary Structure
Biochemistry & Polymer Chemistry
Dimensionless
Local regular folding patterns of a polypeptide backbone stabilised by hydrogen bonds.
Secondary Valence
Inorganic & Coordination Chemistry
Dimensionless
In Werner's theory, the non-ionisable valence corresponding to the coordination number, satisfied by ligands in fixed spatial positions.
Selective Precipitation
Chemical Equilibrium
mol/L
The separation of ions from a mixture by adding a reagent that precipitates them one at a time.
Self-Ionisation of Water
Acids, Bases & Salts
mol/L
The reaction in which two water molecules transfer a proton to give a hydronium and a hydroxide ion.
2H₂O ⇌ H₃O⁺ + OH⁻
SI Base Units
Foundations of Chemistry
Various
The seven defined units of the International System from which every other measurement unit is derived.
Sievert
Nuclear & Radiochemistry
Sv
The SI unit of equivalent dose, weighting absorbed dose by the biological damage the radiation type causes.
H = D × w_R
Slag
Inorganic & Coordination Chemistry
Dimensionless
The molten by-product formed when a flux combines with the gangue during smelting.
Solid State
States of Matter & Gas Laws
Dimensionless
The state of matter in which particles are held in fixed positions, giving a definite shape and volume.
Solubility Rules
Stoichiometry & Chemical Reactions
Dimensionless
A set of empirical guidelines predicting whether an ionic compound will dissolve appreciably in water.
Solution
Solutions & Colligative Properties
Dimensionless
A homogeneous mixture in which one or more substances are dispersed uniformly at the molecular or ionic level in another.
Solvent
Solutions & Colligative Properties
L
The component of a solution present in the greater amount, which dissolves and disperses the solute.
Standard Molar Entropy
Thermochemistry & Thermodynamics
J/(mol·K)
The absolute entropy of one mole of a substance in its standard state at 298 K.
ΔS° = ΣS°(products) − ΣS°(reactants)
Starch
Biochemistry & Polymer Chemistry
Dimensionless
The storage polysaccharide of plants, consisting of amylose and amylopectin.
(C₆H₁₀O₅)ₙ
Stepwise Ionisation
Acids, Bases & Salts
mol/L
The successive loss of protons from a polyprotic acid, each governed by its own equilibrium constant.
Ka₁ ≫ Ka₂ ≫ Ka₃