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Stationary Phase Analytical Chemistry & Spectroscopy Dimensionless The fixed material in a chromatographic system with which the sample components interact as they pass. SN1 Reaction Organic Chemistry s⁻¹ A two-step nucleophilic substitution proceeding through a carbocation intermediate. rate = k[substrate] SN2 Reaction Organic Chemistry L/(mol·s) A single-step nucleophilic substitution in which bond formation and bond breaking occur simultaneously. rate = k[substrate][nucleophile] Solvent Extraction Equilibrium Chemical Equilibrium Dimensionless The equilibrium established when a solute is transferred between two immiscible liquid phases in a separating funnel. efficiency = P V₁ / (P V₁ + V₂) Supercritical Fluid States of Matter & Gas Laws K, Pa A substance held above both its critical temperature and critical pressure, where liquid and gas phases are indistinguishable. T > T_c and p > p_c Salt Acids, Bases & Salts Dimensionless An ionic compound formed when the hydrogen of an acid is replaced by a metal or other cation. acid + base → salt + water Salt Hydrolysis Acids, Bases & Salts mol/L The reaction of a salt's ions with water to produce an acidic or alkaline solution. A⁻ + H₂O ⇌ HA + OH⁻ Scintillation Counter Nuclear & Radiochemistry counts/s A detector in which radiation causes a material to emit flashes of light that are counted and measured. Second Law of Thermodynamics Thermochemistry & Thermodynamics J/K The total entropy of the universe increases in every spontaneous process. ΔS_universe > 0 Secondary Cell Electrochemistry & Redox V A cell whose reaction can be reversed by an applied current, allowing it to be recharged and reused. Secondary Structure Biochemistry & Polymer Chemistry Dimensionless Local regular folding patterns of a polypeptide backbone stabilised by hydrogen bonds. Secondary Valence Inorganic & Coordination Chemistry Dimensionless In Werner's theory, the non-ionisable valence corresponding to the coordination number, satisfied by ligands in fixed spatial positions. Selective Precipitation Chemical Equilibrium mol/L The separation of ions from a mixture by adding a reagent that precipitates them one at a time. Self-Ionisation of Water Acids, Bases & Salts mol/L The reaction in which two water molecules transfer a proton to give a hydronium and a hydroxide ion. 2H₂O ⇌ H₃O⁺ + OH⁻ SI Base Units Foundations of Chemistry Various The seven defined units of the International System from which every other measurement unit is derived. Sievert Nuclear & Radiochemistry Sv The SI unit of equivalent dose, weighting absorbed dose by the biological damage the radiation type causes. H = D × w_R Slag Inorganic & Coordination Chemistry Dimensionless The molten by-product formed when a flux combines with the gangue during smelting. Solid State States of Matter & Gas Laws Dimensionless The state of matter in which particles are held in fixed positions, giving a definite shape and volume. Solubility Rules Stoichiometry & Chemical Reactions Dimensionless A set of empirical guidelines predicting whether an ionic compound will dissolve appreciably in water. Solution Solutions & Colligative Properties Dimensionless A homogeneous mixture in which one or more substances are dispersed uniformly at the molecular or ionic level in another. Solvent Solutions & Colligative Properties L The component of a solution present in the greater amount, which dissolves and disperses the solute. Standard Molar Entropy Thermochemistry & Thermodynamics J/(mol·K) The absolute entropy of one mole of a substance in its standard state at 298 K. ΔS° = ΣS°(products) − ΣS°(reactants) Starch Biochemistry & Polymer Chemistry Dimensionless The storage polysaccharide of plants, consisting of amylose and amylopectin. (C₆H₁₀O₅)ₙ Stepwise Ionisation Acids, Bases & Salts mol/L The successive loss of protons from a polyprotic acid, each governed by its own equilibrium constant. Ka₁ ≫ Ka₂ ≫ Ka₃