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Thermochemistry & Thermodynamics

Standard Molar Entropy

The absolute entropy of one mole of a substance in its standard state at 298 K.

Formula / equation ΔS° = ΣS°(products) − ΣS°(reactants)
Unit J/(mol·K)

In depth

Because the third law fixes a zero, standard entropies are tabulated as absolute values and are always positive for any substance above 0 K. They increase with molecular complexity, molar mass and disorder of the phase, and combine additively to give the entropy change of any reaction.

Examples in the real world

Diamond has a very low 2.4 J/(mol·K) thanks to its rigid lattice; gaseous CO₂ has 214.