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Terms starting with S

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Atomic Structure & Periodicity

Successive Ionisation Energies

The series of energies required to remove electrons one after another from the same atom.

IE₁ < IE₂ < IE₃ … kJ/mol
Acids, Bases & Salts

Superacid

An acid stronger than pure sulfuric acid, capable of protonating species normally regarded as completely non-basic.

H₀ < −12 Dimensionless
States of Matter & Gas Laws

Supercritical Fluid

A substance held above both its critical temperature and critical pressure, where liquid and gas phases are indistinguishable.

T > T_c and p > p_c K, Pa
Solutions & Colligative Properties

Supersaturated Solution

An unstable solution containing more dissolved solute than the equilibrium solubility at that temperature.

mol/L
States of Matter & Gas Laws

Surface Tension

The energy required to increase the surface area of a liquid by unit amount, arising from unbalanced intermolecular forces at the surface.

γ = F / L N/m
Thermochemistry & Thermodynamics

Surroundings

Everything outside the chosen system with which it can exchange energy or matter.

Dimensionless
Thermochemistry & Thermodynamics

System

The specific part of the universe chosen for thermodynamic study, separated from everything else by a real or imaginary boundary.

Dimensionless
Analytical Chemistry & Spectroscopy

Systematic Error

An error that shifts every result in the same direction by a similar amount.

Various