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Inorganic & Coordination Chemistry

Labile and Inert Complexes

The kinetic classification of complexes according to how rapidly they exchange their ligands.

s⁻¹
Chemical Kinetics & Catalysis

Langmuir Adsorption Isotherm

A model describing monolayer adsorption on a surface with a fixed number of equivalent, independent sites.

θ = Kp / (1 + Kp) Dimensionless
States of Matter & Gas Laws

Latent Heat

The energy absorbed or released when a substance changes state, with no accompanying change in temperature.

q = m × L kJ/kg
Chemical Bonding & Molecular Structure

Lattice Energy

The energy released when one mole of an ionic solid is formed from its constituent gaseous ions.

U ∝ (z⁺z⁻) / (r⁺ + r⁻) kJ/mol
Foundations of Chemistry

Law of Conservation of Mass

The principle that the total mass of the substances in a closed system is unchanged by any chemical reaction.

Σ m(reactants) = Σ m(products) kg
Foundations of Chemistry

Law of Definite Proportions

The principle that a given chemical compound always contains its constituent elements in the same fixed mass ratio.

Dimensionless
Chemical Equilibrium

Law of Mass Action

The principle that the rate of a reaction is proportional to the product of the active masses of the reactants.

K = [C]^c[D]^d / [A]^a[B]^b Various
Foundations of Chemistry

Law of Multiple Proportions

The principle that when two elements form more than one compound, the masses of one element combining with a fixed mass of the other are in…

Dimensionless
Nuclear & Radiochemistry

Law of Radioactive Decay

The principle that the rate of decay is proportional to the number of undecayed nuclei present.

N = N₀ e^(−λt) Dimensionless
Stoichiometry & Chemical Reactions

Law of Reciprocal Proportions

The principle that the mass ratios in which two elements combine with a third are related by a simple ratio to the ratio in which they…

Dimensionless
Chemical Equilibrium

Le Chatelier's Principle

When a system at equilibrium is disturbed, it responds in the direction that partially opposes the disturbance.

Dimensionless
Inorganic & Coordination Chemistry

Leaching

The selective dissolution of a metal or its compound from an ore using a suitable chemical reagent.

Dimensionless
Electrochemistry & Redox

Lead–Acid Accumulator

A rechargeable cell using lead and lead dioxide electrodes in sulfuric acid.

Pb + PbO₂ + 2H₂SO₄ ⇌ 2PbSO₄ + 2H₂O V
Acids, Bases & Salts

Levelling Effect

The tendency of a solvent to reduce all acids or bases stronger than its own ionised forms to the same effective strength.

Dimensionless
Chemical Bonding & Molecular Structure

Lewis Structure

A diagram showing the bonding and lone pairs of a molecule using dots or lines for valence electrons.

Dimensionless
Acids, Bases & Salts

Lewis Theory

The theory defining an acid as an electron pair acceptor and a base as an electron pair donor.

A + :B → A←B Dimensionless
Inorganic & Coordination Chemistry

Ligand

An ion or molecule that donates one or more electron pairs to a central metal atom.

Dimensionless
Inorganic & Coordination Chemistry

Ligand Field Theory

The refined bonding model that combines crystal field theory with molecular orbital treatment of metal–ligand covalency.

cm⁻¹
Solutions & Colligative Properties

Like Dissolves Like

The empirical rule that substances dissolve best in solvents with similar polarity and bonding character.

Dimensionless
Analytical Chemistry & Spectroscopy

Limit of Detection

The smallest concentration of analyte that can be reliably distinguished from the blank.

LOD = 3σ_blank / m Various
Analytical Chemistry & Spectroscopy

Limit of Quantitation

The lowest concentration at which the analyte can be measured with acceptable precision and accuracy.

LOQ = 10σ_blank / m Various
Electrochemistry & Redox

Limiting Molar Conductivity

The molar conductivity of an electrolyte extrapolated to infinite dilution, where ionic interactions vanish.

Λ°m S·cm²/mol
Stoichiometry & Chemical Reactions

Limiting Reagent

The reactant that is completely consumed first and therefore determines the maximum amount of product obtainable.

smallest n / coefficient mol
Chemical Bonding & Molecular Structure

Linear Geometry

A molecular shape in which the bonded atoms lie on a straight line, giving a bond angle of 180°.

AX₂ or AX₂E₃ degrees