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Inorganic & Coordination Chemistry

Ligand

An ion or molecule that donates one or more electron pairs to a central metal atom.

Unit Dimensionless

In depth

A ligand must possess at least one lone pair, so it is by definition a Lewis base. Ligands are classified by how many donor atoms they use and by their position in the spectrochemical series, which determines how strongly they split the metal's d orbitals.

Examples in the real world

H₂O, NH₃, Cl⁻, CN⁻ and CO as simple ligands; EDTA as a six-donor ligand.