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Chemical Bonding & Molecular Structure

Linear Geometry

A molecular shape in which the bonded atoms lie on a straight line, giving a bond angle of 180°.

Formula / equation AX₂ or AX₂E₃
Unit degrees

In depth

Linear geometry arises with two electron domains and no lone pairs, or from an octahedral arrangement with four lone pairs. Symmetric linear molecules are always non-polar because opposing bond dipoles cancel exactly, however polar the individual bonds may be.

Examples in the real world

CO₂, BeCl₂ and HCN; the triiodide ion I₃⁻ is linear despite having three lone pairs on the central iodine.