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Chemical Equilibrium

Law of Mass Action

The principle that the rate of a reaction is proportional to the product of the active masses of the reactants.

Formula / equation K = [C]^c[D]^d / [A]^a[B]^b
Unit Various

In depth

Formulated by Guldberg and Waage, the law leads directly to the equilibrium constant expression, in which products appear in the numerator and reactants in the denominator, each raised to its stoichiometric coefficient. It is the foundation of all quantitative equilibrium calculation.

Examples in the real world

For N₂ + 3H₂ ⇌ 2NH₃ the law gives K = [NH₃]² / ([N₂][H₂]³).